دورية أكاديمية

Technical note: RA138 Calcite U-Pb LA-ICP-MS primary reference material.

التفاصيل البيبلوغرافية
العنوان: Technical note: RA138 Calcite U-Pb LA-ICP-MS primary reference material.
المؤلفون: Guillong, Marcel, Samankassou, Elias, Müller, Inigo A., Szymanowski, Dawid, Looser, Nathan, Tavazzani, Lorenzo, Merino-Tomé, Óscar, Bahamonde, Juan R., Buret, Yannick, Ovtcharova, Maria
المصدر: Geochronology; 3/6/2024, p1-16, 16p
مصطلحات موضوعية: LASER ablation inductively coupled plasma mass spectrometry, REFERENCE sources, CALCITE, URANIUM-lead dating
مصطلحات جغرافية: SPAIN
مستخلص: A promising primary reference material for U-Pb LA-ICP-MS carbonate dating is analysed and reported here. The new RM is a botryoidal cement (C1) from sample RA138. The sample was collected in outcrop strata of mid-Carboniferous (Uppermost Mississippian, upper Serpukhovian) in northern Spain near La Robla, and multiple aliquots have been meticulously prepared for distribution. The RA138 is characterised by variable U/Pb ratios (from ~1 to ~19) and a relatively high and homogeneous U content (~4 ppm). This material exhibits a low age uncertainty (0.2 %, 2s; unanchored, ID-TIMS), allowing for the establishment of a well-defined isochron, particularly when anchored to the initial Pb ratio using LA-ICP-MS. ID-TIMS analyses of micro drilled C1 cement (17 sub-samples) produce a lower intercept age of 321.99 ± 0.65 Ma, an initial 207Pb/206Pb ratio of 0.8495 ± 0.0065, and a Mean Square of Weighted Deviations (MSWD) of 5.1. The systematic uncertainty of 1.5 % observed in repeated LA-ICP-MS analyses challenges previous estimations of 2–2.5 % based on repeated analyses of ASH-15D and JT using WC-1 as primary reference material, underscoring the precision and reliability of RA138 for U-Pb dating applications. [ABSTRACT FROM AUTHOR]
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قاعدة البيانات: Complementary Index
الوصف
تدمد:26283697
DOI:10.5194/gchron-2024-7