التفاصيل البيبلوغرافية
| العنوان: |
A novel energetic pyridine-2-carbohydrazide copper perchlorate complex: synthesis, cationic ligand structure and properties. |
| المؤلفون: |
Kuang, Bao-long, Lu, Zu-jia, Zhao, Bin-shan, Wang, Ting-wei, Sun, Mou, Zhang, Chao, Xu, Mei-qi, Yu, Qi-yao, Zhang, Jian-guo |
| المصدر: |
New Journal of Chemistry; 5/7/2024, Vol. 48 Issue 17, p7946-7952, 7p |
| مصطلحات موضوعية: |
COPPER compounds, FURAZANS, ELEMENTAL analysis, THERMAL stability, INFRARED spectroscopy, THERMAL properties, EXPLOSIVES |
| مستخلص: |
To synthesize lead-free primary explosives with good thermal stability, pyridine-2-carbohydrazide (2-PDCA) was used to prepare a novel energetic copper perchlorate complex (ECCs-1), which was structurally characterized by infrared spectroscopy, NMR, and elemental analysis. Its thermal decomposition properties were investigated by thermogravimetry and a synchrotron thermal analyzer, and the sensitivity was tested by the BAM method. The laser ignition experiment and the lead plate tests show that the ECCs-1 complex has a good detonation performance with a high thermal decomposition temperature (215.6 °C) and moderate sensitivity (impact sensitivity = 3 J and friction sensitivity = 5 N). [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
Complementary Index |
