التفاصيل البيبلوغرافية
| العنوان: |
anti -Selective Synthesis of Substituted β-Homoprolines by Rhodium Alkyl Nitrene C–H Insertion. |
| المؤلفون: |
Tang, Xinxin, Noda, Hidetoshi, Shibasaki, Masakatsu |
| المصدر: |
Synlett; Jun2024, Vol. 35 Issue 10, p1131-1134, 4p |
| مصطلحات موضوعية: |
RHODIUM, INDUSTRIAL chemistry, RHODIUM catalysts, METHOXY group, ACID derivatives, AZIRIDINATION |
| مستخلص: |
This article discusses the synthesis of substituted β-homoprolines using rhodium catalysis. β-Homoproline is a variant of α-proline and is found in natural products and pharmaceuticals. The article describes the development of a new method for synthesizing β-homoprolines, which involves the cyclization of isoxazolidin-5-ones using a rhodium catalyst. The authors demonstrate the scope and limitations of this method and discuss the downstream transformations that can be performed on the resulting β-homoprolines. Overall, this research provides valuable insights into the synthesis and potential applications of β-homoprolines. [Extracted from the article] |
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| قاعدة البيانات: |
Complementary Index |
