التفاصيل البيبلوغرافية
| العنوان: |
Crystal structure of 1-(1,3-benzothiazol-2-yl)-3-(4- bromobenzoyl)thiourea. |
| المؤلفون: |
Sow, Salif, Thiam, Mariama, Odame, Felix, Thiam, Elhadj Ibrahima, Diouf, Ousmane, Ellen, Javier, Gaye, Mohamed, Tshentu, Zenixole |
| المصدر: |
Acta Crystallographica Section E: Crystallographic Communications; Jun2024, Vol. 80 Issue 7, Following p663-666, 6p |
| مصطلحات موضوعية: |
CRYSTAL structure, DIHEDRAL angles, CHEMICAL reactions, THIOUREA, HYDROGEN bonding, POTASSIUM |
| مستخلص: |
The chemical reaction of 4-bromobenzoylchloride and 2-aminothiazole in the presence of potassium thiocyanate yielded a white solid formulated as C15H10BrN3OS2, which consists of 4-bromobenzamido and 2-benzothiazolyl moieties connected by a thiourea group. The 4-bromobenzamido and 2-benzothiazolyl moieties are in a trans conformtion (sometimes also called s-trans due to the single bond) with respect to the N—C bond. The dihedral angle between the mean planes of the 4-bromophenyl and the 2-benzothiazolyl units is 10.45 (11)°. The thiourea moiety, —C—NH—C(=S) —NH— fragment forms a dihedral angle of 8.64 (12)° with the 4-bromophenyl ring and is almost coplanar with the 2-benzothiazolyl moiety, with a dihedral angle of 1.94 (11)°. The molecular structure is stabilized by intramolecular N—H⋯O hydrogen bonds, resulting in the formation of an S(6) ring. In the crystal, pairs of adjacent molecules interact via intermolecular hydrogen bonds of type C—H⋯N, C—H⋯S and N—H⋯S, resulting in molecular layers parallel to the ac plane. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
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