التفاصيل البيبلوغرافية
| العنوان: |
A chelated borinium cation. |
| المؤلفون: |
Major, Christopher, Lough, Alan, Stephan, Douglas W. |
| المصدر: |
Dalton Transactions: An International Journal of Inorganic Chemistry; 6/28/2024, Vol. 53 Issue 24, p10075-10078, 4p |
| مصطلحات موضوعية: |
BORENIUM ions, FLUORIDES, BORON, DIAMIDES, SALTS, CATIONS |
| مستخلص: |
Two coordinate boron cations are rare. Herein we report the synthesis of [RNSiMe2CH2]2BF (R = Dipp 3, 1-Ad 5) (Dipp = C6H3(iPr)2, Ad = C10H15) via the reaction of BF3 with the corresponding dilithiated diamides. Subsequent abstraction of fluoride provided the corresponding borinium salts, [(RNSiMe2CH2)2B][B(C6F5)4] (R = Dipp 6, 1-Ad 8). While the former was generated, the latter proved isolable and was crystallographically characterized. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
Complementary Index |
