دورية أكاديمية

Sulfidation of Iron - Based Nanomaterial as Catalyst for Water Splitting Using Hydrothermal.

التفاصيل البيبلوغرافية
العنوان: Sulfidation of Iron - Based Nanomaterial as Catalyst for Water Splitting Using Hydrothermal.
المؤلفون: Ayu Ardi Lestari, Ni Luh, Arjana, I Gede, Putu Mardana, Ida Bagus
المصدر: Journal of Comprehensive Science (JCS); May2024, Vol. 3 Issue 5, p1-14, 14p
مصطلحات موضوعية: GREENHOUSE gas mitigation, IRON sulfides, RENEWABLE energy sources, FERRIC hydroxides, HYDROGEN evolution reactions
مستخلص: Consumption of fossil fuels causes greenhouse effect and global warming, hence the need for renewable energy sources that are environmentally friendly. Hydrogen is one of the abundant elements on earth. Hydrogen refers to a clean and renewable energy source, hydrogen can be a good choice to reduce greenhouse gas emissions. One way to produce hydrogen is by electrochemical water splitting. This study aims to determine the characterization of iron-based nanomaterials (iron sulfide - iron hydroxide) as a water splitting catalyst in general. Iron sulfide synthesis was carried out using hydrothermal sulfidation method for 6 hours at 80 oC with nickel foam as substrate. Synthesis of iron sulfide varying the concentration of sodium sulfide nonahydrate (0.0125 M, 0.025 M, 0.05 M and 0.1 M) produced brownish yellow to blackish grey colored samples. Characterization results using XRD showed that iron sulfide peaks were detected at higher concentrations of sodium sulfide nonahydrate. Based on the results of analyzing iron hydroxide using SEM, it is known that the sample is in the form of nano walls and on iron sulfide, it is known that the sample is in the form of nanoscale particles. Based on electrochemical measurement results, iron hydroxide can be a good catalyst for hydrogen evolution reaction (HER) compared with commercial Pt/C. The overpotential of iron hydroxide is smaller than Pt/C, which is only 15 mV at a current density 10 mA/cm2 and iron sulfide can be a good catalyst for oxygen evolution reaction (OER) with electrocatalytic measurement results close to commercial RuO2. This is indicated by the small overpotential (260 mV at current densisty 10 mA/cm2 and small tafel slope (51 mV/dec). [ABSTRACT FROM AUTHOR]
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قاعدة البيانات: Complementary Index
الوصف
تدمد:29624738
DOI:10.59188/jcs.v3i5.728