التفاصيل البيبلوغرافية
| العنوان: |
Hydrazido complexes prepared by methylation of an anionic end-on bridging dinitrogen dititanium complex. |
| المؤلفون: |
Ishida, Yutaka, Nakanishi, Yusuke, Hiratsuka, Takuma, Kawaguchi, Hiroyuki |
| المصدر: |
Chemical Communications; 7/25/2024, Vol. 60 Issue 58, p7459-7462, 4p |
| مصطلحات موضوعية: |
METHYLATION, METHYL iodide, PHENOXIDES, SILYLATION, CARBOXYLATION, TITANIUM, NITROGEN |
| مستخلص: |
Here we report stepwise methylation of end-on bridging dinitrogen to a hydrazido ligand to a pentamethylhydrazinium salt, which is mediated by a titanium system with a tripodal aryloxide supporting ligand. The results constitute a synthetic cycle for pentamethylhydrazinium formation from dinitrogen and methyl iodide. We also describe silylation of the dinitrogen complex and carboxylation of the hydrazido complex. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
Complementary Index |
