التفاصيل البيبلوغرافية
| العنوان: |
Iron‐Catalyzed C−H Alkylation/Ring Opening with Vinylbenzofurans Enabled by Triazoles. |
| المؤلفون: |
Cattani, Silvia, Pandit, Neeraj Kumar, Buccio, Michele, Balestri, Davide, Ackermann, Lutz, Cera, Gianpiero |
| المصدر: |
Angewandte Chemie International Edition; 8/5/2024, Vol. 63 Issue 32, p1-7, 7p |
| مستخلص: |
We report an unprecedented iron‐catalyzed C−H annulation using readily available 2‐vinylbenzofurans as the reaction pattern. The redox‐neutral strategy, based on cheap, non‐toxic, and earth‐abundant iron catalysts, exploits triazole assistance to promote a cascade C−H alkylation, benzofuran ring‐opening and insertion into a Fe−N bond, to form highly functionalized isoquinolones. Detailed mechanistic studies supported by DFT calculations fully disclosed the manifold of the iron catalysis. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
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