التفاصيل البيبلوغرافية
| العنوان: |
Chirality Sensing of Cryptochiral Guests with Prism[n]arenes. |
| المؤلفون: |
Della Sala, Paolo, Calice, Umberto, Iuliano, Veronica, Geremia, Silvano, Hickey, Neal, Belviso, Sandra, Summa, Francesco F., Monaco, Guglielmo, Gaeta, Carmine, Superchi, Stefano |
| المصدر: |
Chemistry - A European Journal; 7/16/2024, Vol. 30 Issue 40, p1-9, 9p |
| مصطلحات موضوعية: |
PLANAR chirality, CIRCULAR dichroism, CHIRALITY, AROMATIC compounds, MIXTURES |
| مستخلص: |
Optical chirality sensing has gained significant attention in recent years. Within this field, the quest for stereodynamic chiroptical probes capable of detecting cryptochiral guests presents a formidable challenge. Macrocycles exhibiting planar chirality have emerged as promising candidates for amplifying the chirality of cryptochiral guests. In this study, we demonstrate that the formation of host‐guest complexes between cryptochiral molecules and planar chiral prismarenes triggers electronic circular dichroism (ECD) signals via host‐guest complexation‐induced chirality amplification. The absolute configuration of the most stable chiral macrocyclic host‐guest complex has been established by resorting to both exciton model and DFT computations. Furthermore, we demonstrated that this supramolecular chirality sensing system can be employed to determine the enantiomeric composition of scalemic mixtures by measuring the ECD bands intensity. The information described here opens the way for the use of prismarenes as stereodynamic probes for sensing of cryptochiral guests. [ABSTRACT FROM AUTHOR] |
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