التفاصيل البيبلوغرافية
| العنوان: |
The Development of the Theory of Strong Electrolyte Solutions. |
| المؤلفون: |
Alexandr Zaitsev, Vladimir Afanasiev |
| المصدر: |
Journal of Solution Chemistry; Oct2008, Vol. 37 Issue 10, p1425-1436, 12p |
| مصطلحات موضوعية: |
ELECTROLYTE solutions, GIBBS' free energy, HYDRATION, SOLUTION (Chemistry), IONS |
| مستخلص: |
Abstract The expression for Gibbs energy of electrolyte solutions has been derived taking into account the contribution of interactions of the hydrated shells of ions. It is in good agreement with data for the dependence of the hydration number on concentration. The contribution of different interactions to the activity coefficient depending on concentration has been analyzed. The possibility of determining parameters which characterize the composition of hydrated shells of individual atoms from experimental data has been considered. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
Complementary Index |
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