دورية أكاديمية

Mass spectrometry of the trimethylsilyl derivatives of some cardiac aglycones and monoglycosides.

التفاصيل البيبلوغرافية
العنوان: Mass spectrometry of the trimethylsilyl derivatives of some cardiac aglycones and monoglycosides.
المؤلفون: Falkner, Fred C., Frölich, Jürgen, Watson, J. Throck
المصدر: Organic Mass Spectrometry; 1973, Vol. 7 Issue 2, p141-153, 13p
مستخلص: Mass spectra of the trimethylsilyl (TMS) ethers of digitoxigenin, digoxigenin, digitoxigenin monodigitoxoside, digoxigenin monodigitoxoside and peruvoside were obtained. Ions appearing at m/e 170 and m/e 183 are proposed to be indicative of the enol TMS ether moiety as confirmed by appropriate shifts in the mass spectrum of digitoxigenin derivatized with perdeuterotrimethylsilylating reagent. The TMS ether derivatives of the monoglycosides produced abundant molecular ions and the base peaks in the spectra represent fragments of the sugar portion of the molecule. [ABSTRACT FROM AUTHOR]
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قاعدة البيانات: Complementary Index
الوصف
تدمد:0030493X
DOI:10.1002/oms.1210070204