التفاصيل البيبلوغرافية
| العنوان: |
Cyano Bridged Bimetallic Compounds of the Type M2+-NC-Fe3+ (M = Co, Ni, Cu, Zn, Cd) Using the [Fe(CN)6]6 Building Block and their Antibacterial Evaluation. |
| المؤلفون: |
Uddin, Mohammad Nasir, Akter, Jashmin, Manchur, Mohammed Abul |
| المصدر: |
Orbital: The Electronic Journal of Chemistry; Oct-Dec2013, Vol. 5 Issue 4, p257-263, 7p |
| مصطلحات موضوعية: |
CHEMICAL reactions, CHEMICAL energy, CHEMICAL processes, BIMETALLIC catalysts, CYANIDES synthesis, LIGAND biosynthesis |
| مستخلص: |
Reactions between [M(L)]2+ [M= Cu(II), Co(II), Cd(II), Zn(II) and Ni(II)] and [Fe(CN)6]3- give rise to cyano-bridged assembled bimetallic complexes. Their structures have been proposed by elemental analyses, IR, UV-VIS and 13C NMR spectra, conductance and magnetic measurements studies. The structure is supposed to consist of zigzag chains formed by an alternate array of the cations and [Fe(CN)6]3- anion having neutral Ni3Fe2 units. Each hexacyanoferrate(III) ion connects three nickel(II) ions using three cis CN- groups and the remaining CN- groups are terminal. The bridging cyanide ligands co-ordinate to the metal ion in a trans fashion forming trans-ML(CN)2 moieties. Antibacterial activity of some of the prepared complexes has also been investigated against three human pathogen bacteria. [ABSTRACT FROM AUTHOR] |
|
Copyright of Orbital: The Electronic Journal of Chemistry is the property of Orbital: The Electronic Journal of Chemistry and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) |
| قاعدة البيانات: |
Complementary Index |
Full Text Finder