التفاصيل البيبلوغرافية
| العنوان: |
A cyano-bridged tubular coordination polymer with dominant ferromagnetic interactions. |
| المؤلفون: |
Peng-Fei Zhuang, Tao Liu, Xian-Hui Xie, Cheng He, Chun-Ying Duan |
| المصدر: |
Dalton Transactions: An International Journal of Inorganic Chemistry; 2015, Vol. 44 Issue 2, p464-467, 4p |
| مصطلحات موضوعية: |
COORDINATION polymers synthesis, FERROMAGNETIC materials, COORDINATION compounds, MAGNETIC properties, INTERMOLECULAR interactions, SURFACE chemistry |
| مستخلص: |
It is a challenge to synthesize a porous tubular coordination polymer with magnetic properties. Utilizing [FeII(bipy)(CN)4]²- (bipy = 2,2'- bipyridine) as the building block to react with Mn2+, we successfully synthesized a cyano-bridged tubular coordination polymer with dominant ferromagnetic interactions. The inner surface of the heterometallic tube is hydrophilic, whereas the outer surface is hydrophobic. The framework is stable up to 320 °C and can adsorb N2 and CO2. The ferromagnetic interactions were transmitted via the diamagnetic N - C - FeII-C-N species between Mn2+ions in the tube. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
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