التفاصيل البيبلوغرافية
| العنوان: |
Electrochemical ammonia oxidation catalyzed by ruthenium complexes: investigation of substituent effect of axial pyridine ligands. |
| المؤلفون: |
Hiroki Toda, Ryoichi Kanega, Tasuku Yano, Takeshi Yoshikawa, Shogo Kuriyama, Yuichiro Himeda, Ken Sakata, Yoshiaki Nishibayashi |
| المصدر: |
Chemistry Letters; Mar2024, Vol. 53 Issue 3, p1-4, 4p |
| مستخلص: |
We have examined catalytic ammonia oxidation using ruthenium complexes bearing 2,2'-bipyridine-6,6'-dicarboxylate ligand and axial 3- and 4-substituted pyridine ligands under electrochemical conditions to study the substituent effect of the axial pyridine ligands. Ruthenium complex bearing 3,4-dibromopyridine ligands shows the highest catalytic activity to produce up to 145 equivalents of dinitrogen based on the catalyst. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
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