دورية
A Linear Solvation Free Energy Relationship Analysis of Solubilization in Mixed Cationic−Nonionic Micelles
| العنوان: | A Linear Solvation Free Energy Relationship Analysis of Solubilization in Mixed Cationic−Nonionic Micelles |
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| المؤلفون: | Rodrigues, M. A., Alonso, E. O., Yihwa, C., Farah, J. P. S., Quina, F. H. |
| المصدر: | Langmuir; September 28, 1999, Vol. 15 Issue: 20 p6770-6774, 5p |
| مستخلص: | Incorporation coefficients for binding of 29 nonionic solutes to cationic/nonionic mixed micelles (1:1 molar ratio of hexadecyltrimethylammonium bromide (CTAB)/ polyoxyethylene[23]dodecyl ether (Brij 35)) were employed to establish a linear solvation free energy relationship (LSER) based on five solute parameters. Comparison of this LSER with those for solute incorporation into micelles of the pure, unmixed detergents indicates that hydrogen-bonding interactions are the predominant contributors to the nonidealities of solubilization in the mixed micelle. |
| قاعدة البيانات: | Supplemental Index |
Find this issue from the American Chemical Society | تدمد: | 07437463 15205827 |
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