التفاصيل البيبلوغرافية
العنوان: |
Total Syntheses of (±)-Preussomerins G and I |
المؤلفون: |
Chi, S., Heathcock, C. H. |
المصدر: |
Organic Letters; July 1999, Vol. 1 Issue: 1 p3-6, 4p |
مستخلص: |
Preussomerins G and I (2 and 3) have been synthesized for the first time. The key reaction in the synthesis is a possibly biomimetic tautomerization reaction depicted in Scheme 3 and the foregoing graphic. The driving force for this interesting rearrangement is primarily derived from the increase in resonance energy associated with converting a naphthalene ring into two isolated benzene rings. |
قاعدة البيانات: |
Supplemental Index |