Synthesis and single crystal X-ray structure of the first cationic Pd(ii) complex of a tellurium-containing polyaza macrocycle: contrasting reactions of Pd(ii) and Pt(ii) with a 22-membered macrocyclic Schiff base

التفاصيل البيبلوغرافية
العنوان: Synthesis and single crystal X-ray structure of the first cationic Pd(ii) complex of a tellurium-containing polyaza macrocycle: contrasting reactions of Pd(ii) and Pt(ii) with a 22-membered macrocyclic Schiff base
المؤلفون: Menon, Saija C., Panda, Arunashree, Singh, Harkesh B., Butcher, Ray J.
المصدر: Chemical Communications; January 21, 2000, Vol. 2000 Issue: 2 p143-144, 2p
مستخلص: The reaction of the tellurium containing macrocyclic Schiff base 1 with Pd(PhCN)2Cl2 and NH4PF6 gives the expected cationic complex [PdII1][PF6]2; by contrast the reaction of 1 with Pt(cod)Cl2 proceeds via novel transmetallation to yield an organoplatinum complex.
قاعدة البيانات: Supplemental Index