دورية
Synthesis, characterization, and structural investigations of 1amino3substituted1,2,3triazolium salts, and a new route to 1substituted1,2,3triazoles
| العنوان: | Synthesis, characterization, and structural investigations of 1amino3substituted1,2,3triazolium salts, and a new route to 1substituted1,2,3triazoles |
|---|---|
| المؤلفون: | Kaplan, Greg, Drake, Greg, Tollison, Kerri, Hall, Leslie, Hawkins, Tommy |
| المصدر: | Journal of Heterocyclic Chemistry; January 2005, Vol. 42 Issue: 1 p19-27, 9p |
| مستخلص: | Quarternary salts based upon 3alkyl substituted 1amino1,2,3triazolium cations alkyl methyl, ethyl, nypropyl, 2propenyl, and nbutyl have been synthesized and characterized by vibrational spectra, multinuclear NMR, elemental analysis, and DSC studies. Subsequent diazotization of these salts results in the exclusive formation of 1alkyl1,2,3triazoles. Single crystal Xray studies were carried out for 1amino3methyl1,2,3triazolium iodide, 1amino3ethyl1,2,3triazolium bromide, 1amino3npropyl1,2,3triazolium bromide, and 1amino3nbutyl1,2,3triazolium bromide as well as the starting heterocycle, 1amino1,2,3triazole, and all of the structures are discussed. |
| قاعدة البيانات: | Supplemental Index |
Full Text Finder | تدمد: | 0022152X 19435193 |
|---|---|
| DOI: | 10.1002/jhet.5570420104 |