[Me2Al(THF)2]⁺[{Me2Si(NDipp)2}2Zr2Cl5]^- (Dipp = 2,6-Diisopropylphenyl), an Unusual Zirconium/Aluminum Ion Pair Containing a THF-Stabilized Dimethylaluminum Cation

التفاصيل البيبلوغرافية
العنوان:	[Me2Al(THF)2]⁺[{Me2Si(NDipp)2}2Zr2Cl5]^- (Dipp = 2,6-Diisopropylphenyl), an Unusual Zirconium/Aluminum Ion Pair Containing a THF-Stabilized Dimethylaluminum Cation
المؤلفون:	Hill, M. S., Hitchcock, P. B.
المصدر:	Organometallics; July 2002, Vol. 21 Issue: 15 p3258-3262, 5p
مستخلص:	The bulky chelating dianion Me2Si(NDipp^-)2 has been used to synthesize [{Me2Si(NDipp)2}ZrCl2(THF)2] (Dipp = 2,6-diisopropylphenyl). Reaction of Al2Me6 and [{Me2Si(NDipp)2}ZrCl2(THF)2] affords the unusual ionic complex [Me2Al(THF)2]⁺[{Me2Si(NDipp)2}2Zr2Cl5]^-.
قاعدة البيانات:	Supplemental Index

الوصف
تدمد:	02767333 15206041
DOI:	10.1021/om0201819

[Me2Al(THF)2]+[{Me2Si(NDipp)2}2Zr2Cl5]- (Dipp = 2,6-Diisopropylphenyl), an Unusual Zirconium/Aluminum Ion Pair Containing a THF-Stabilized Dimethylaluminum Cation