دورية
Mechanorphore-Based Poly(Glycidyl Methacrylate) Synthesized by Atom Transfer Living Radical Polymerization
| العنوان: | Mechanorphore-Based Poly(Glycidyl Methacrylate) Synthesized by Atom Transfer Living Radical Polymerization |
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| المؤلفون: | Liu, Xiao Bing, Gong, Fei Yan |
| المصدر: | Applied Mechanics and Materials; October 2014, Vol. 670 Issue: 1 p249-252, 4p |
| مستخلص: | Mechanorphore-based Poly (glycidyl methacrylate) was synthesized by atom transfer radical polymerization (ATRP) of glycidyl methacrylate (GMA) in bulk by using spiropyran-based initiator, CuCl in combination with N,N,N’,N’’,N’’-pentamethyldiethylenetriamine (PMDETA) as catalyst. The resultant polymer was characterized by gel permeation chromatography (GPC) and 1H NMR spectroscopy. The relative molecular mass of PGMA can be changed by polymerization time. The resultant polymers have controlled molecular weight and low polydispersity. The present synthetic strategy provides a convenient and efficient method to synthesize mechanophore-linked PGMA which can be ulteriorly crosslinked to form thermosetting polymer networks. |
| قاعدة البيانات: | Supplemental Index |
Full Text Finder | تدمد: | 16609336 16627482 |
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| DOI: | 10.4028/www.scientific.net/AMM.670-671.249 |