دورية
Highly diastereoselective dihydride formation by activation of methanol with IrCl{(S)-binap}(PPh3)
| العنوان: | Highly diastereoselective dihydride formation by activation of methanol with IrCl{(S)-binap}(PPh3) |
|---|---|
| المؤلفون: | Tani, Kazuhide, Nakajima, Kouji, Iseki, Aika, Yamagata, Tsuneaki |
| المصدر: | Chemical Communications; August 21, 2001, Vol. 2001 Issue: 17 p1630-1631, 2p |
| مستخلص: | Reaction of [IrCl{(S)-binap}(PPh3)] {(S)-3} with methanol gave one of the diastereomers of the cis,mer-dihydride, cis,mer-OC-6-44-A-[IrCl(H2){(S)-binap}(PPh3)] {(S)-4a} stereoselectively, the structure of which was determined crystallographically, whereas the reaction of (S)-3 with H2 produced a 1∶1 mixture of the diastereomers of the cis,mer-dihydride, (S)-4a and cis,mer-OC-6-44-C-[IrCl(H2){(S)-binap}(PPh3)] {(S)-4b}. |
| قاعدة البيانات: | Supplemental Index |
| تدمد: | 13597345 1364548X |
|---|