Long-range two-dimensional ¹H²⁹Si heteronuclear shift correlation using gradients. Application to tetra-TMS-α-O-methyl-D-glucopyranose and tetra-TES-α-O-methyl-D-glucopyranose

التفاصيل البيبلوغرافية
العنوان:	Long-range two-dimensional ¹H²⁹Si heteronuclear shift correlation using gradients. Application to tetra-TMS-α-O-methyl-D-glucopyranose and tetra-TES-α-O-methyl-D-glucopyranose
المؤلفون:	Provera, Stefano, Davalli, Silvia, Raza, Giorgio H., Contini, Stefania, Marchioro, Carla
المصدر:	Magnetic Resonance in Chemistry; January 2001, Vol. 39 Issue: 1 p38-42, 5p
مستخلص:	The gradient-enhanced ¹H,²⁹Si HMQC experiment was applied to tetra-TMS-α-O-methyl-D-glucopyranose and tetra-TES-α-O-methyl-D-glucopyranose as test samples. All the expected ²J(¹H, ²⁹Si) and ³J (¹H,²⁹Si) cross peaks were observed, allowing the full ²⁹Si NMR assignment. An analysis of the trend of ²⁹Si chemical shifts depending on the position of the silylating group in the sugar ring and on the different hindrances of TMS and TES groups is also reported. Copyright © 2001 John Wiley & Sons, Ltd.
قاعدة البيانات:	Supplemental Index

الوصف
تدمد:	07491581 1097458X

Long-range two-dimensional 1H29Si heteronuclear shift correlation using gradients. Application to tetra-TMS-α-O-methyl-D-glucopyranose and tetra-TES-α-O-methyl-D-glucopyranose