التفاصيل البيبلوغرافية
العنوان: |
Application of Response Surface Methodology for Optimization of Cadmium Ion Removal from an Aqueous Solution by Eggshell Powder |
المؤلفون: |
Sabah, Hajji, Thouraya, Turki, Melek, Hajji, Nadia, Mzoughi |
المصدر: |
Chemical Research in Chinese Universities; 20240101, Issue: Preprints p1-9, 9p |
مستخلص: |
The removal of cadmium(Cd) from synthetic solutions by batch adsorption process was performed using eggshell powder, which is mainly composed of calcite(CaCO3). In order to optimize the adsorption process, a re-sponse surface methodology(RSM) based on Central Composite Design(CCD) was applied. Developed model for Cd remo- val yields(R, %) response was statistically validated by variance analysis(ANOVA) which showed a high de-termination coefficient value(R2=0.9889). According to Minitab software, the optimal conditions were found at tem-perature of 44 °C, eggshell adsorbent dose of 2.98 g, initial Cd concentration of 36.74 mg/L and initial pH of 7. Un-der these conditions, the Cd removal yield was 98.76%. The deviation value of 1.24% confirms the validity of the model for the adsorption process optimization. The adsorption isotherm has been described by a Freundlich model. In addition, the predominant sorption mechanisms are the chemisorptions or precipitation(non-reversible) and ion ex-change(reversible). |
قاعدة البيانات: |
Supplemental Index |