التفاصيل البيبلوغرافية
| العنوان: |
Ru(II)-Catalyzed C–H Aminocarbonylation of N-(Hetero)aryl-7-azaindoles with Isocyanates |
| المؤلفون: |
Jeong, Taejoo, Lee, Suk Hun, Chun, Rina, Han, Sangil, Han, Sang Hoon, Jeon, Yeong Uk, Park, Jihye, Yoshimitsu, Takehiko, Mishra, Neeraj Kumar, Kim, In Su |
| المصدر: |
The Journal of Organic Chemistry; 20240101, Issue: Preprints |
| مستخلص: |
The ruthenium(II)-catalyzed C–H aminocarbonylation of N-(hetero)aryl-7-azaindoles with isocyanates is described. The excellent site selectivity at the ortho-position within the N-(hetero)aryl ring was observed to provide ortho-amidated N-(hetero)aryl-7-azaindoles under the mild reaction conditions. The resulting 7-azaindole derivatives can be readily transformed into 7-azaindoles containing carboxylic acid and alkyl amine functional groups. |
| قاعدة البيانات: |
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