التفاصيل البيبلوغرافية
| العنوان: |
Enantioselective total synthesis of (+)-vincamine |
| المؤلفون: |
Xue, Fanglin, Liu, Hengmao, Wang, Rui, Zhang, Dan, Song, Hao, Liu, Xiao-Yu, Qin, Yong |
| المصدر: |
Chinese Chemical Letters; 20210101, Issue: Preprints |
| مستخلص: |
A catalytic asymmetric total synthesis of (+)-vincamine is presented. Key features of the synthesis include a Pd-catalyzed enantioselective decarboxylative allylation to form the C20 quaternary stereogenic center and a stereoselective iminium reduction to install the critical cis-C20/C21 relative stereochemisty. |
| قاعدة البيانات: |
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