دورية
Separation of Americium(III) from Lanthanide by Encapsulating Hexadentate-ligand
العنوان: | Separation of Americium(III) from Lanthanide by Encapsulating Hexadentate-ligand |
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المؤلفون: | Watanabe, Masayuki, Mirvaliev, Rinat, Tachimori, Shoichi, Takeshita, Kenji, Nakano, Yoshio, Morikawa, Koshi, Mori, Ryohei |
المصدر: | Chemistry Letters; December 2002, Vol. 31 Issue: 12 p1230-1231, 2p |
مستخلص: | Am(III) is encapsulated in an aqueous phase by a podand-type ligand, N,N,N′,N′-tetrakis(2-methylpyridyl)ethylenediamine (TPEN), and is extracted selectively over trivalent lanthanide in an organic phase using nitrobenzene. The extraction of Am(III) using TPEN shows higher selectivity and chemical stability than other conventional ones using nitrogen-donor ligands. |
قاعدة البيانات: | Supplemental Index |
تدمد: | 03667022 13480715 |
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DOI: | 10.1246/cl.2002.1230 |