دورية
First platinum clusters containing a direct Pt–Si bond: molecular structure of [Pt3{Si(OSiMe3)3}(µ-PPh2)3(PPh3)2] and electrochemical studies
| العنوان: | First platinum clusters containing a direct Pt–Si bond: molecular structure of [Pt3{Si(OSiMe3)3}(µ-PPh2)3(PPh3)2] and electrochemical studies |
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| المؤلفون: | Bender, Robert, Braunstein, Pierre, Bouaoud, Salah-Eddine, Merabet, Naima, Rouag, Djamil, Zanello, Piero, Fontani, Marco |
| المصدر: | New Journal of Chemistry; June 7, 1999, Vol. 23 Issue: 11 p1045-1047, 3p |
| مستخلص: | The reaction of [Pt3Ph(µ-PPh2)3(PPh3)2] (1) with various silanes and siloxanes afforded the first platinum clusters containing a direct Pt–Si bond that could be characterized by X-ray diffraction, in the case of [Pt3{Si(OSiMe3)3}(µ-PPh2)3(PPh3)2] (2a): the redox properties of the 44-electron clusters 1 and [Pt3{Si(OMe)3}(µ-PPh2)3(PPh3)2] (2b) have been studied by cyclic voltammetry. |
| قاعدة البيانات: | Supplemental Index |
| تدمد: | 11440546 13699261 |
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| DOI: | 10.1039/a905840k |