Fotokemijske transformacije 2-klor-5-[2-(2-etenilfenil)etenil]tiofena

التفاصيل البيبلوغرافية
العنوان: Fotokemijske transformacije 2-klor-5-[2-(2-etenilfenil)etenil]tiofena
المؤلفون: Ćibarić, Katarina
المساهمون: Vuk, Dragana
سنة النشر: 2018
مصطلحات موضوعية: thiophene, electrocyclization, PRIRODNE ZNANOSTI. Kemija. Organska kemija, NATURAL SCIENCES. Chemistry. Organic Chemistry, cikloadicija, Wittig reaction, tiofen, elektrociklizacija, o-divinylbenzene, Wittigova reakcija, o-divinilbenzen, tiofen, o-divinilbenzen, Wittigova reakcija, cikloadicija, elektrociklizacija, cycloaddition
الوصف: Cilj ovog rada je proučavanje fotokemijskog ponašanja derivata β-supstituiranog 5-klortiofenskog derivata o-divinilbenzena 1. Spoj 1 sintetiziran je Wittigovom reakcijom u dva stupnja, te je dobiven u obliku smjese cis- i trans- izomera koji su izolirani i spektroskopski okarakterizirani. Napravljena su preliminarna fotokemijska ispitivanja nakon čega je spoj 1 podvrgnut fotokemijskom ispitivanju, pri čemu su izolirana tri nova intramolekulska produkta. The aim of this work is to study the photochemical behavior of 5-chlorothiophene derivative of o-divinylbenzene 1. Compound 1 was synthesized by two-step Wittig reaction and it was obtained as a mixture of cis- and trans-isomers which were isolated and spectroscopically characterized. Prepared compound was subjected to photochemical irradiation, which gave three new intramolecular products. The new photoproducts were isolated and specroscopically characterized.
وصف الملف: application/pdf
اللغة: Croatian
URL الوصول: https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::fab54e8636f9953334aafb240c6a1d10
https://www.bib.irb.hr/956997
حقوق: OPEN
رقم الأكسشن: edsair.dedup.wf.001..fab54e8636f9953334aafb240c6a1d10
قاعدة البيانات: OpenAIRE