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Enantioselective synthesis of protected α-aminoketones via electrophilic amination of α-silylketones with an oxaziridine

التفاصيل البيبلوغرافية
العنوان:	Enantioselective synthesis of protected α-aminoketones via electrophilic amination of α-silylketones with an oxaziridine
المؤلفون:	Dieter Enders, Christine Poiesz, Reni Joseph
المصدر:	Tetrahedron: Asymmetry. 9:3709-3716
بيانات النشر:	Elsevier BV, 1998.
سنة النشر:	1998
مصطلحات موضوعية:	Silylation, Organic Chemistry, Enantioselective synthesis, Buffer solution, Tetrabutylammonium fluoride, Oxaziridine, Medicinal chemistry, Catalysis, Inorganic Chemistry, chemistry.chemical_compound, Enantiopure drug, chemistry, Electrophilic amination, Physical and Theoretical Chemistry, Enantiomer
الوصف:	N-Boc protected α-aminoketones ( 4 ) of moderate enantiomeric purity were synthesised via N-Boc-3-(4-cyanophenyl)-oxaziridine ( 5 ) mediated electrophilic amination of enantiopure α-silyl ketones ( 2 ) followed by removal of the silyl directing group in the aminated products ( 3 ) with tetrabutylammonium fluoride in a buffer solution.
تدمد:	0957-4166
URL الوصول:	https://explore.openaire.eu/search/publication?articleId=doi_________::04c020465e5e3cbf2bd4c3a9b142f0fd https://doi.org/10.1016/s0957-4166(98)00382-6
حقوق:	CLOSED
رقم الأكسشن:	edsair.doi...........04c020465e5e3cbf2bd4c3a9b142f0fd
قاعدة البيانات:	OpenAIRE

الوصف
تدمد:	09574166