Reactivity of (NHC)2FeX2 Complexes toward Arylborane Lewis Acids and Arylboronates
| العنوان: | Reactivity of (NHC)2FeX2 Complexes toward Arylborane Lewis Acids and Arylboronates |
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| المؤلفون: | Michael J. Ingleson, Kathlyn L. Fillman, Michael L. Neidig, Ian A. Cade, Jay J. Dunsford |
| المصدر: | Organometallics. 33:370-377 |
| بيانات النشر: | American Chemical Society (ACS), 2013. |
| سنة النشر: | 2013 |
| مصطلحات موضوعية: | Inorganic Chemistry, chemistry.chemical_compound, chemistry, Aryl, Organic Chemistry, Organic chemistry, Lewis acids and bases, Physical and Theoretical Chemistry, Methoxide, Medicinal chemistry, Dissociation (chemistry) |
| الوصف: | (NHC)2FeCl2 complexes undergo methoxide transfer in preference to aryl transfer from [(Aryl)B(OR)3]−, while addition of ArylBY2 (Y = Cl, OR) to (NHC)Fe–methoxide compounds leads only to formation of (NHC)BY2Aryl. The addition of PhBCl2 to (NHC)2FeX2 compounds is introduced as a method for probing NHC dissociation from iron. Two expanded ring NHCs also undergo dissociation from iron in the respective (NHC)2FeCl2 complexes. |
| تدمد: | 1520-6041 0276-7333 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::067f3bc7198dacba8702f0e79716112b https://doi.org/10.1021/om401105k |
| رقم الأكسشن: | edsair.doi...........067f3bc7198dacba8702f0e79716112b |
| قاعدة البيانات: | OpenAIRE |
Find this issue from the American Chemical Society | تدمد: | 15206041 02767333 |
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