Relationship between (micro)structure and functional (photocatalytic and adsorption) properties of anatase–mordenite nanocomposite
العنوان: | Relationship between (micro)structure and functional (photocatalytic and adsorption) properties of anatase–mordenite nanocomposite |
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المؤلفون: | Andrey S. Orekhov, Vera V. Klechkovskaya, E. N. Domoroshchina, Vladimir V. Chernyshev, G. V. Kravchenko, Galina M. Kuz’micheva, Larisa V. Pirutko |
المصدر: | Research on Chemical Intermediates. 45:2869-2885 |
بيانات النشر: | Springer Science and Business Media LLC, 2019. |
سنة النشر: | 2019 |
مصطلحات موضوعية: | Anatase, chemistry.chemical_compound, Nanocomposite, Adsorption, Materials science, X-ray photoelectron spectroscopy, Chemical engineering, Electron diffraction, chemistry, Photocatalysis, Methyl orange, General Chemistry, Mordenite |
الوصف: | Anatase–mordenite nanocomposite was synthesized in situ and characterized by X-ray diffraction analysis, Brunauer–Emmett–Teller measurements, infrared (IR) spectroscopy, electron diffraction measurements, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, and scanning and transmission electron microscopy. It was found that X-ray-amorphous anatase located in the zeolite micropores resulted in a decrease in the specific surface of anatase–mordenite compared to the initial mordenite. Anatase-containing nanoparticles in anatase–mordenite showed round shape and formed nano-associates and conglomerates. The water content in the zeolite cavities in anatase–mordenite was lower compared to mordenite. Anatase–mordenite nanocomposite exhibited higher photocatalytic activity in the model decomposition reaction of methyl orange under ultraviolet (UV) radiation and higher adsorption capacity for extraction of P(V) and As(V) ions from aqueous environment in the dark compared to the initial mordenite or anatase due to an increase in the content of active OH-groups on the nanocomposite surface compared to mordenite and an increase in the specific surface compared to anatase. |
تدمد: | 1568-5675 0922-6168 |
URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::073e3a187d0a33503dfb83be85a3ed7a https://doi.org/10.1007/s11164-019-03767-7 |
حقوق: | CLOSED |
رقم الأكسشن: | edsair.doi...........073e3a187d0a33503dfb83be85a3ed7a |
قاعدة البيانات: | OpenAIRE |
تدمد: | 15685675 09226168 |
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