Relationship between (micro)structure and functional (photocatalytic and adsorption) properties of anatase–mordenite nanocomposite

التفاصيل البيبلوغرافية
العنوان: Relationship between (micro)structure and functional (photocatalytic and adsorption) properties of anatase–mordenite nanocomposite
المؤلفون: Andrey S. Orekhov, Vera V. Klechkovskaya, E. N. Domoroshchina, Vladimir V. Chernyshev, G. V. Kravchenko, Galina M. Kuz’micheva, Larisa V. Pirutko
المصدر: Research on Chemical Intermediates. 45:2869-2885
بيانات النشر: Springer Science and Business Media LLC, 2019.
سنة النشر: 2019
مصطلحات موضوعية: Anatase, chemistry.chemical_compound, Nanocomposite, Adsorption, Materials science, X-ray photoelectron spectroscopy, Chemical engineering, Electron diffraction, chemistry, Photocatalysis, Methyl orange, General Chemistry, Mordenite
الوصف: Anatase–mordenite nanocomposite was synthesized in situ and characterized by X-ray diffraction analysis, Brunauer–Emmett–Teller measurements, infrared (IR) spectroscopy, electron diffraction measurements, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, and scanning and transmission electron microscopy. It was found that X-ray-amorphous anatase located in the zeolite micropores resulted in a decrease in the specific surface of anatase–mordenite compared to the initial mordenite. Anatase-containing nanoparticles in anatase–mordenite showed round shape and formed nano-associates and conglomerates. The water content in the zeolite cavities in anatase–mordenite was lower compared to mordenite. Anatase–mordenite nanocomposite exhibited higher photocatalytic activity in the model decomposition reaction of methyl orange under ultraviolet (UV) radiation and higher adsorption capacity for extraction of P(V) and As(V) ions from aqueous environment in the dark compared to the initial mordenite or anatase due to an increase in the content of active OH-groups on the nanocomposite surface compared to mordenite and an increase in the specific surface compared to anatase.
تدمد: 1568-5675
0922-6168
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::073e3a187d0a33503dfb83be85a3ed7a
https://doi.org/10.1007/s11164-019-03767-7
حقوق: CLOSED
رقم الأكسشن: edsair.doi...........073e3a187d0a33503dfb83be85a3ed7a
قاعدة البيانات: OpenAIRE