New Azo Chromophore-Containing Conjugated Polymers: Facile Synthesis by Using 'Click' Chemistry and Enhanced Nonlinear Optical Properties Through the Introduction of Suitable Isolation Groups

التفاصيل البيبلوغرافية
العنوان: New Azo Chromophore-Containing Conjugated Polymers: Facile Synthesis by Using 'Click' Chemistry and Enhanced Nonlinear Optical Properties Through the Introduction of Suitable Isolation Groups
المؤلفون: Cheng Ye, Jingui Qin, Zhong'an Li, Gui Yu, Zhen Li, Qi Zeng, Yunqi Liu
المصدر: Macromolecular Rapid Communications. 29:136-141
بيانات النشر: Wiley, 2008.
سنة النشر: 2008
مصطلحات موضوعية: chemistry.chemical_classification, Azo compound, Polymers and Plastics, Chemistry, Organic Chemistry, Second-harmonic generation, Nonlinear optics, Polymer, Conjugated system, Chromophore, Combinatorial chemistry, chemistry.chemical_compound, Polymer chemistry, Materials Chemistry, Click chemistry, Thermal stability
الوصف: A new series of azobenzene-containing polyfluorenes have been successfully prepared through polymer reactions by the utilization of "click" chemistry. All the polymers were well characterized and soluble in common solvents. By the application of the concept of "suitable isolation group", the macroscopic nonlinear optical (NLO) properties of the polymers could be boosted to as large as three times that of the polymer without isolation moieties. Also, all the polymers were thermally stable, and demonstrated good procesability, coupled with improved optical transparency. Thus, they are good candidates for the practical applications as new photonic materials.
تدمد: 1521-3927
1022-1336
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::14da931e9535e6f430e09f5d3174704d
https://doi.org/10.1002/marc.200700599
حقوق: CLOSED
رقم الأكسشن: edsair.doi...........14da931e9535e6f430e09f5d3174704d
قاعدة البيانات: OpenAIRE