Effect of Ag+ Cations on Nonoxidative Activation of Methane to C2-Hydrocarbons
| العنوان: | Effect of Ag+ Cations on Nonoxidative Activation of Methane to C2-Hydrocarbons |
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| المؤلفون: | Ding Ma, Qingjun Zhu, Dali Tan, Shutian Zhou, Xinhe Bao, Yan Wang, Shaojun Miao, Lingling Su |
| المصدر: | The Journal of Physical Chemistry B. 108:17866-17871 |
| بيانات النشر: | American Chemical Society (ACS), 2004. |
| سنة النشر: | 2004 |
| مصطلحات موضوعية: | Reaction mechanism, Aqueous solution, Chemistry, Inorganic chemistry, Methane, Surfaces, Coatings and Films, Catalysis, Ion, chemistry.chemical_compound, Reaction sequence, Materials Chemistry, Density functional theory, Physical and Theoretical Chemistry, Metal clusters |
| الوصف: | Nonoxidative activation of methane was carried out over Ag/ZSM-5 catalysts, prepared by the wetness impregnation method, and the catalysts were characterized by various techniques. Theoretical calculation was further employed to clarify the reaction mechanism of methane coupling over the catalysts. Ag+ ions were found to be the main Ag species at low loading (1−5 wt %) whereas higher loading (10 wt %) resulted in metal clusters. Combined with experimental evidence and computer modeling, it is concluded that isolated Ag+ ions play a crucial role in the catalytic coupling of methane under nonoxidative conditions. |
| تدمد: | 1520-5207 1520-6106 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::18663d3950cbfbd9361079d73883df28 https://doi.org/10.1021/jp047209+ |
| رقم الأكسشن: | edsair.doi...........18663d3950cbfbd9361079d73883df28 |
| قاعدة البيانات: | OpenAIRE |
Find this issue from the American Chemical Society | تدمد: | 15205207 15206106 |
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