أعرض في EDS

Reaction of imidazole derivatives with trifluoromethylated arylacetylenes

التفاصيل البيبلوغرافية
العنوان: Reaction of imidazole derivatives with trifluoromethylated arylacetylenes
المؤلفون: Vasily M. Muzalevskiy, Andrei V. Afonin, Kseniya V. Belyaeva, Lina P. Nikitina, Vladimir B. Kobychev, Valentine G. Nenajdenko, Boris A. Trofimov, Ludmila V. Andriyankova, Igor A. Ushakov, Anastasiya G. Mal'kina
المصدر: Journal of Fluorine Chemistry. 188:157-163
بيانات النشر: Elsevier BV, 2016.
سنة النشر: 2016
مصطلحات موضوعية: Trifluoromethyl, Nucleophilic addition, 010405 organic chemistry, Organic Chemistry, Regioselectivity, 010402 general chemistry, Triple bond, 01 natural sciences, Biochemistry, Medicinal chemistry, 0104 chemical sciences, Adduct, Inorganic Chemistry, chemistry.chemical_compound, Acetylene, chemistry, Environmental Chemistry, Imidazole, Organic chemistry, Stereoselectivity, Physical and Theoretical Chemistry
الوصف: The nucleophilic addition of imidazole derivatives to trifluoromethylated acetylenes was studied. Unpredictable regioselectivity of the reaction was observed to yield both β- and α-addition products. The reaction is 100% stereoselective to give the corresponding adducts as a Z -isomers only. The observed regioselectivity is discussed in terms of polarization of triple bond using experimental and calculated data.
تدمد: 0022-1139
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::1ceeb93a5b0a234377753d1b2b1d82a4
https://doi.org/10.1016/j.jfluchem.2016.06.013
حقوق: CLOSED
رقم الأكسشن: edsair.doi...........1ceeb93a5b0a234377753d1b2b1d82a4
قاعدة البيانات: OpenAIRE
الوصف
تدمد:00221139