Synthesis, characterizations and catalytic allylic oxidation of limonene to carvone of cobalt doped mesoporous silica templated by reed leaves

التفاصيل البيبلوغرافية
العنوان: Synthesis, characterizations and catalytic allylic oxidation of limonene to carvone of cobalt doped mesoporous silica templated by reed leaves
المؤلفون: Jiaqiang Wang, Dong Xue, Junjie Li, Zhongrui Luo, Zhiqiang Li, Guoli Zi, Wang Baoqi, Wang Yanmei, Zhiang Yao
المصدر: Catalysis Communications. 59:233-237
بيانات النشر: Elsevier BV, 2015.
سنة النشر: 2015
مصطلحات موضوعية: Limonene, Carvone, Allylic rearrangement, Process Chemistry and Technology, chemistry.chemical_element, General Chemistry, Mesoporous silica, Catalysis, Acetic anhydride, chemistry.chemical_compound, chemistry, Organic chemistry, Selectivity, Cobalt
الوصف: Reeds (Phragmites communis) leaves were successfully used as template in synthesis of cobalt doped mesoporous silica (Co/SiO2/PC). The catalyst exhibited very high substrate conversion (100%) and relatively good product (carvone) selectivity (40.2%) for allylic oxidation of limonene to carvone using air as oxidant and acetic anhydride as solvent without adding any initiator. Fast hot catalyst filtration experiment proved that the catalyst acted as a heterogeneous one and it can be recycled easily and reused two times without significant loss of activity and selectivity.
تدمد: 1566-7367
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::20b7b5b471c60f0f2c75ec666dbe4b30
https://doi.org/10.1016/j.catcom.2014.10.022
حقوق: OPEN
رقم الأكسشن: edsair.doi...........20b7b5b471c60f0f2c75ec666dbe4b30
قاعدة البيانات: OpenAIRE