The Effect of Rh Particle Size on the Catalytic Performance of Porous Silica supported Rhodium Catalysts for CO Hydrogenation
| العنوان: | The Effect of Rh Particle Size on the Catalytic Performance of Porous Silica supported Rhodium Catalysts for CO Hydrogenation |
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| المؤلفون: | Shutian Zhou, Mojie Cheng, Xinhe Bao, Shaojun Miao, Ding Ma, Hong Zhao |
| المصدر: | Zeitschrift für Physikalische Chemie. 219:949-961 |
| بيانات النشر: | Walter de Gruyter GmbH, 2005. |
| سنة النشر: | 2005 |
| مصطلحات موضوعية: | Materials science, Inorganic chemistry, chemistry.chemical_element, Catalysis, Rhodium, Metal, Adsorption, chemistry, visual_art, visual_art.visual_art_medium, Particle, Particle size, Physical and Theoretical Chemistry, Selectivity, Porosity |
| الوصف: | Silica-supported Rh catalysts with different Rh particle dimensions were investigated for CO hydrogenation. The catalysts were characterized by various techniques such as TEM, H2-TPR and N2 adsorption to study the catalyst morphology, the size distributions of Rh particles and the silica pores. It was found that the distribution and the size of Rh particles were affected by the silica pores, and the metal grains were enclosed in the pores of the support, and thereby their growth was limited. The catalytic activity and selectivity to C2-oxygenates for CO hydrogenation were found to be significantly controlled by the Rh particle sizes, and the higher activity and selectivity to C2-oxygenates were obtained over bigger Rh particles, within the range of the reported particle sizes. |
| تدمد: | 2196-7156 0942-9352 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::2390dcde6a7997d832bc2f11be8ca5c9 https://doi.org/10.1524/zpch.219.7.949.67093 |
| رقم الأكسشن: | edsair.doi...........2390dcde6a7997d832bc2f11be8ca5c9 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 21967156 09429352 |
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