Methyl triphenylphosphonium permanganate as a novel oxidant for aniline to polyaniline-manganese(II, IV) oxide: material for high performance pseudocapacitor
| العنوان: | Methyl triphenylphosphonium permanganate as a novel oxidant for aniline to polyaniline-manganese(II, IV) oxide: material for high performance pseudocapacitor |
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| المؤلفون: | Rajender Boddula, Susmitha Uppugalla, Palaniappan Srinivasan |
| المصدر: | Journal of Solid State Electrochemistry. 22:407-415 |
| بيانات النشر: | Springer Science and Business Media LLC, 2017. |
| سنة النشر: | 2017 |
| مصطلحات موضوعية: | Permanganate, Inorganic chemistry, Emulsion polymerization, 02 engineering and technology, 010402 general chemistry, 021001 nanoscience & nanotechnology, Condensed Matter Physics, 01 natural sciences, Interfacial polymerization, 0104 chemical sciences, chemistry.chemical_compound, Aniline, chemistry, Polymerization, Polyaniline, Pseudocapacitor, Electrochemistry, General Materials Science, Electrical and Electronic Engineering, Cyclic voltammetry, 0210 nano-technology, Nuclear chemistry |
| الوصف: | In this work, organic-inorganic composite materials of polyaniline and manganese oxide were synthesized and investigated their electrochemical performance. This composite material was prepared by oxidizing aniline with methyl triphenylphosphonium permanganate as a novel organic oxidant via aqueous, emulsion, and interfacial polymerization pathways. This process led to the formation of polyaniline-sulfate salt (PANI-SA-Mn5O8). Formation of polyaniline-sulfate salt was confirmed from FT-IR, EDAX, and XRD results. Formation of Mn5O8 was supported by XRD spectrum. PANI-SA-Mn5O8 prepared via emulsion polymerization pathway was obtained in porous nanorod morphology with high conductivity (9.4 S cm−1) compared to that of the other sample prepared via interfacial pathway (1.7 S cm−1). Whereas, aqueous polymerization pathway resulted in sheet-like morphology with a conductivity of 0.8 S cm−1. These composites were used as pseudocapacitive electrode materials. Electrochemical characterization (cyclic voltammetry, charge-discharge, and electrochemical impedance measurement) showed that composite prepared via emulsion polymerization pathway gave better electrochemical performance, and showed good cycling behavior. |
| تدمد: | 1433-0768 1432-8488 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::26708ba0cc4ca38f0ea0afa5349dc129 https://doi.org/10.1007/s10008-017-3770-5 |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi...........26708ba0cc4ca38f0ea0afa5349dc129 |
| قاعدة البيانات: | OpenAIRE |
Find this article in full text from Springer Verlag. | تدمد: | 14330768 14328488 |
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