Transference Numbers for Sodium and Potassium Chlorides in Anhydrous Methanol at 25°C
| العنوان: | Transference Numbers for Sodium and Potassium Chlorides in Anhydrous Methanol at 25°C |
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| المؤلفون: | J. A. Davies, A. R. Gordon, R. L. Kay |
| المصدر: | The Journal of Chemical Physics. 19:749-751 |
| بيانات النشر: | AIP Publishing, 1951. |
| سنة النشر: | 1951 |
| مصطلحات موضوعية: | Aqueous solution, Potassium, Sodium, Inorganic chemistry, General Physics and Astronomy, chemistry.chemical_element, Ion, Solvent, chemistry.chemical_compound, chemistry, Anhydrous, Triiodobenzoate, Methanol, Physical and Theoretical Chemistry |
| الوصف: | Transference numbers have been determined by the moving boundary method for sodium chloride in anhydrous methanol at concentrations from 0.003 N to 0.01 N, and for potassium chloride at concentrations from 0.005 N to 0.02 N. Autogenic cells were used for cation boundaries and sheared cells (with paratoluenesulfonate, di‐ and triiodobenzoate as indicator ions) for anion boundaries. The results are comparable in precision with those for aqueous solutions and satisfy all criteria for transference data. The Longsworth function is linear in the concentration up to 0.01 N, thus making it possible for the first time to obtain precise limiting transference numbers in an anhydrous solvent. |
| تدمد: | 1089-7690 0021-9606 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::2a93c2b2eb78ae9f1d5b11525a4869be https://doi.org/10.1063/1.1748345 |
| رقم الأكسشن: | edsair.doi...........2a93c2b2eb78ae9f1d5b11525a4869be |
| قاعدة البيانات: | OpenAIRE |
Find this article in full text from Scitation. | تدمد: | 10897690 00219606 |
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