Microstructure effects on the electrochemical corrosion of carbon materials and carbon-supported Pt catalysts

التفاصيل البيبلوغرافية
العنوان: Microstructure effects on the electrochemical corrosion of carbon materials and carbon-supported Pt catalysts
المؤلفون: Svetlana V. Cherepanova, Pavel A. Simonov, Vladimir I. Zaikovskii, Alexandr N. Simonov, N. S. Moseva, Olga V. Cherstiouk, Elena R. Savinova
المصدر: Electrochimica Acta. 55:8453-8460
بيانات النشر: Elsevier BV, 2010.
سنة النشر: 2010
مصطلحات موضوعية: Physics, chemistry.chemical_classification, General Chemical Engineering, chemistry.chemical_element, Nanotechnology, Polymer, Carbon black, Electrolyte, Microstructure, Corrosion, Catalysis, chemistry, Chemical engineering, Electrochemistry, Carbon, Electrode potential
الوصف: The electrochemical corrosion behavior of a set of porous carbonaceous materials of interest as catalyst supports for polymer electrolyte membrane fuel cells was examined in 2 M H 2 SO 4 at 80 °C at constant electrode potential of 1.2 V vs. RHE. Correlations have been observed between the specific rates of corrosion of carbon materials and carbon-supported Pt catalysts on the one hand and their substructural characteristics derived from X-ray diffraction analysis on the other hand. Carbon supports of the Sibunit family and catalytic filamentous carbons possess lower specific (i.e., surface area normalized) corrosion currents compared to conventional furnace black Vulcan XC-72 and better stabilize Pt nanoparticles.
تدمد: 0013-4686
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::2ed286d5e22be7dd5f8066531faea860
https://doi.org/10.1016/j.electacta.2010.07.047
حقوق: CLOSED
رقم الأكسشن: edsair.doi...........2ed286d5e22be7dd5f8066531faea860
قاعدة البيانات: OpenAIRE