Based on the background of modern art education, this study understands the teaching mode, analyzes the current situation of painting teaching with low learning efficiency, points out the future development trend of art education, and solves the problem of lack of individualized art teaching demand. This paper proposes a “Individualized Painting Education Model” based on user experience and AI technology. This mode of education improves learners' painting level from three aspects. First, it provides learners with accurate learning materials immediately. Secondly, individualized guidance should be given according to learners' learning objectives. Finally, the learner's work is evaluated professionally. Based on the individualized painting education model, this study develops the “Individualized Painting Teaching System”, which consists of community module, painting creation module, painting auxiliary module and individual center. The research results show that learners can effectively improve their learning efficiency and artistic creation ability through the application of individualized painting education model, so as to enhance their interest in fine arts and painting.