ChemInform Abstract: Nucleophilic Substitution in the 10,11-Dihydrodibenz[b,f]iodepinium Cation
| العنوان: | ChemInform Abstract: Nucleophilic Substitution in the 10,11-Dihydrodibenz[b,f]iodepinium Cation |
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| المؤلفون: | T. P. Tolstaya, Nikolay A. Bumagin, L. I. Sukhomlinova, A. N. Vanchikov |
| المصدر: | ChemInform. 31 |
| بيانات النشر: | Wiley, 2010. |
| سنة النشر: | 2010 |
| مصطلحات موضوعية: | Substitution reaction, chemistry.chemical_compound, Aqueous solution, Tetrafluoroborate, chemistry, Nucleophilic substitution, Organic chemistry, General Medicine, Phenanthrene, Medicinal chemistry, Ion |
| الوصف: | 10,11-Dihydrodibenz[b,f]iodepinium tetrafluoroborate gave only 1-(2-azidophenyl)-2-(2-iodophenylethane with the N3− in aqueous DMSO, while with NO2− it gave 1-(2-nitrophenyl)-2-(2-iodophenyl)ethane (93%), 9,10-dihydrophenanthrene (5%), and traces of phenanthrene. Both in pure and aqueous DMSO this cation with the Br− ion was converted into phenanthrene (80% and 68% respectively) and 1-(2-bromophenyl)-2-(2-iodophenyl)ethane (10 and 20%), while in water it gave 9,10-dihydrophenanthrene (75%) and phenanthrene (5%). A new route for the synthesis of 1-(2-aminophenyl)-2-phenylethane starting from this tetrafluoroborate has been proposed. |
| تدمد: | 1522-2667 0931-7597 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::30ae86eca59f70692f75279c457b7d21 https://doi.org/10.1002/chin.200001047 |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi...........30ae86eca59f70692f75279c457b7d21 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 15222667 09317597 |
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