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Oxidative radical phosphonotrifluoromethylthiolation of unactivated alkenes with alkyl phosphonate, silver(I) trifluoromethanethiolate and potassium persulfate

التفاصيل البيبلوغرافية
العنوان:	Oxidative radical phosphonotrifluoromethylthiolation of unactivated alkenes with alkyl phosphonate, silver(I) trifluoromethanethiolate and potassium persulfate
المؤلفون:	Yongan Liu, Zhiwei Xiao, Liping Zheng, Xiumiao Zhou, Qing-Yun Chen, Yong Guo, Chao Liu, Youzhuan Xie
المصدر:	Tetrahedron. 74:6213-6219
بيانات النشر:	Elsevier BV, 2018.
سنة النشر:	2018
مصطلحات موضوعية:	chemistry.chemical_classification, 010405 organic chemistry, Radical, Organic Chemistry, Potassium persulfate, Oxidative phosphorylation, 010402 general chemistry, 01 natural sciences, Biochemistry, Medicinal chemistry, Phosphonate, 0104 chemical sciences, Umpolung, chemistry.chemical_compound, chemistry, Drug Discovery, Functional group, Alkyl
الوصف:	We report herein a mild and efficient oxidative radical intermolecular phosphonotrifluoromethylthiolation of unactivated alkenes with good functional group tolerance. The reaction operates via a radical pathway involving oxidative generation of phosphonyl radicals and umpolung radical coupling of silver trifluoromethanethiolate.
تدمد:	0040-4020
URL الوصول:	https://explore.openaire.eu/search/publication?articleId=doi_________::3450b953555e8bbd5a82fbfa57553f2f https://doi.org/10.1016/j.tet.2018.09.019
حقوق:	CLOSED
رقم الأكسشن:	edsair.doi...........3450b953555e8bbd5a82fbfa57553f2f
قاعدة البيانات:	OpenAIRE

الوصف
تدمد:	00404020