ChemInform Abstract: Confirmation of the Stereostructure of (+)-Cytostatin by Fluorous Mixture Synthesis of Four Candidate Stereoisomers
| العنوان: | ChemInform Abstract: Confirmation of the Stereostructure of (+)-Cytostatin by Fluorous Mixture Synthesis of Four Candidate Stereoisomers |
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| المؤلفون: | Won-Hyuk Jung, Dennis P. Curran, John Mancuso, Shuichi Nakamura, Concepcion Riesco‐Fagundo, Sabrina Guyenne |
| المصدر: | ChemInform. 39 |
| بيانات النشر: | Wiley, 2008. |
| سنة النشر: | 2008 |
| مصطلحات موضوعية: | Cytostatin, Chemistry, Computational chemistry, General Medicine, Optical rotation, Chemical equation |
| الوصف: | Mix and match: Four closely related candidate isomers for cytostatin have been synthesized by using the technique of fluorous mixture synthesis. Comparison of NMR, thin-layer chromatography, and optical rotation data enabled the three isomers that were not cytostatin to be identified. Thus, by a process of elimination (disproof), the isomer corresponding to cytostatin was determined, and the 4S,5S,6S,9S,10S,11S configuration confirmed. (Chemical Equation Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA. |
| تدمد: | 1522-2667 0931-7597 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::35452d4d337f698e053527be641d86f9 https://doi.org/10.1002/chin.200823202 |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi...........35452d4d337f698e053527be641d86f9 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 15222667 09317597 |
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