The organocatalytic synthesis of perfluorophenylsulfides via the thiolation of trimethyl(perfluorophenyl)silanes and thiosulfonates
| العنوان: | The organocatalytic synthesis of perfluorophenylsulfides via the thiolation of trimethyl(perfluorophenyl)silanes and thiosulfonates |
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| المؤلفون: | Jinyun Luo, Leifang Wu, Zhihua Cai, Lin He, Muze Lin, Guang-Fen Du |
| المصدر: | Organic & Biomolecular Chemistry. 19:9237-9241 |
| بيانات النشر: | Royal Society of Chemistry (RSC), 2021. |
| سنة النشر: | 2021 |
| مصطلحات موضوعية: | Reaction conditions, chemistry.chemical_compound, Silanes, chemistry, Organic Chemistry, Superbase, Organic chemistry, Physical and Theoretical Chemistry, Biochemistry, Catalysis |
| الوصف: | The organic superbase t-Bu-P4-catalyzed direct thiolation of trimethyl(perfluorophenyl)silanes and thiosulfonates was developed. Yields of perfluorophenylsulfides of up to 97% under catalysis of 5 mol% t-Bu-P4 were achieved. This method was shown to provide an efficient way to construct the perfluorophenyl–sulfur bond under mild metal-free reaction conditions. |
| تدمد: | 1477-0539 1477-0520 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::379a01e87d7fbbd79f67b73dc4834e15 https://doi.org/10.1039/d1ob01350e |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi...........379a01e87d7fbbd79f67b73dc4834e15 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 14770539 14770520 |
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