Half-sandwich Ru(ii ) arene complexes bearing benzimidazole ligands for the N-alkylation reaction of aniline with alcohols in a solvent-free medium
| العنوان: | Half-sandwich Ru( |
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| المؤلفون: | Metin Çiçek, Namık Özdemir, Nevin Gürbüz, Esin Ispir, İsmail Özdemir |
| المصدر: | New Journal of Chemistry. 45:11075-11085 |
| بيانات النشر: | Royal Society of Chemistry (RSC), 2021. |
| سنة النشر: | 2021 |
| مصطلحات موضوعية: | Benzimidazole, 010405 organic chemistry, Borrowing hydrogen, chemistry.chemical_element, General Chemistry, Carbon-13 NMR, Alkylation, 010402 general chemistry, 01 natural sciences, Catalysis, 0104 chemical sciences, Ruthenium, chemistry.chemical_compound, Aniline, chemistry, Polymer chemistry, Materials Chemistry, Proton NMR |
| الوصف: | In this article, the direct N-alkylation reactions of amines with alcohol derivatives using the borrowing hydrogen methodology have been investigated. For this purpose, a new series of half-sandwich ruthenium(II) complexes bearing N-coordinated benzimidazole complexes have been synthesized and fully characterized by FT-IR, 1H NMR and 13C NMR spectroscopies. Additionally, the structures of the complexes 2a–2e have been characterized by X-ray crystallography. All new complexes were investigated for their catalytic activities in the alkylation reaction of amines with alcohol derivatives. It was found that alkylation reactions in a solvent-free medium are efficient and selective. |
| تدمد: | 1369-9261 1144-0546 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::537c517170289eb5b7d1bb10f5dccdaf https://doi.org/10.1039/d1nj01539g |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi...........537c517170289eb5b7d1bb10f5dccdaf |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 13699261 11440546 |
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