Synthesis of modified β-cyclodextrin polymers and characterization of their fuchsin adsorption
| العنوان: | Synthesis of modified β-cyclodextrin polymers and characterization of their fuchsin adsorption |
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| المؤلفون: | Xiao Mei Zhang, Cheng Song Peng, Guo Cai Xu |
| المصدر: | Journal of Inclusion Phenomena and Macrocyclic Chemistry. 72:165-171 |
| بيانات النشر: | Springer Science and Business Media LLC, 2011. |
| سنة النشر: | 2011 |
| مصطلحات موضوعية: | chemistry.chemical_classification, Aqueous solution, Morphology (linguistics), Cyclodextrin, Chemistry, Amidogen, Contact time, General Chemistry, Polymer, Water insoluble, Condensed Matter Physics, chemistry.chemical_compound, Adsorption, Polymer chemistry, Food Science |
| الوصف: | Three water insoluble β-cyclodextrin polymers HP-β-CDP, CM-β-CDP and AE-β-CDP were synthesized by cross-linking epoxychloropropane with corresponding β-CD derivatives and utilized to adsorb water-soluble dye fuchsin from aqueous solution. FT-IR spectra confirmed the existence of hydroxypropyl, carboxyl group and amidogen in polymers. The influences of several parameters (contact time, pH and temperature) and the degree of substitution (DS) of CM-β-CDP in range of 1.5–4.5 on the adsorption capacity (Q e) were evaluated. The results showed that all maximum Q e of polymers appeared at pH 5.2–5.3. CM-β-CDP with carboxyl group was the most effective extractant, and the Q e of CM-β-CDP with DS 1.5–2.5 kept nearly constant but decreased sharply over 2.5. However, AE-β-CDP with amidogen had displayed a quite low Q e to fuchsin, even lower than that of unmodified β-CD polymer. The preliminary studies on the morphology of both CM-β-CDP and AE-β-CDP by AFM disclosed the differences in topography of their surfaces. |
| تدمد: | 1573-1111 0923-0750 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::54d74815d607d50747b84f6e3f5b7525 https://doi.org/10.1007/s10847-011-9956-z |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi...........54d74815d607d50747b84f6e3f5b7525 |
| قاعدة البيانات: | OpenAIRE |
Find this article in full text from Springer Verlag. | تدمد: | 15731111 09230750 |
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