Modification of Tefzel film through graft copolymerization
العنوان: | Modification of Tefzel film through graft copolymerization |
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المؤلفون: | Baljit Singh, Inderjeet Kaur, B. N. Misra, Neelam Sharma, Nirupma Gupta |
المصدر: | Polymer International. 53:1572-1580 |
بيانات النشر: | Wiley, 2004. |
سنة النشر: | 2004 |
مصطلحات موضوعية: | chemistry.chemical_classification, Thermogravimetric analysis, Materials science, Polymers and Plastics, Organic Chemistry, Polymer, Grafting, Styrene, chemistry.chemical_compound, surgical procedures, operative, Monomer, Chemical engineering, chemistry, Methacrylonitrile, Polymer chemistry, Materials Chemistry, Copolymer, Thermal stability |
الوصف: | The graft copolymerization of styrene (st) and methacrylonitrile (MAN) onto Tefzel film in aqueous media by the preirradiation method has been studied. In order to follow the effect of preswelling of the backbone polymer, grafting was attempted onto preirradiated Tefzel film and monomer preswollen, preirradiated Tefzel film. Optimum conditions pertaining to maximum percentage of grafting of st and MAN have been evaluated. Grafting onto preswollen, preirradiated Tefzel film displayed better results. The effect of different alcohols of increasing chain length on the percentage of grafting of st and MAN was also studied. Graft copolymerization of st showed an increase, while grafting with MAN exhibited a decrease, in the percentage of grafting in the presence of alcohols as compared to that obtained in the aqueous medium. Characterization of the graft copolymers was made by IR and thermogravimetric studies. Tefzel-graft-polystyrene showed improved thermal stability while the MAN grafted onto preswollen, preirradiated Tefzel film produced graft copolymer with poor thermal stability. Copyright © 2004 Society of Chemical Industry |
تدمد: | 1097-0126 0959-8103 |
URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::550d26bf84bb6e49737e4758cc810b31 https://doi.org/10.1002/pi.1444 |
حقوق: | CLOSED |
رقم الأكسشن: | edsair.doi...........550d26bf84bb6e49737e4758cc810b31 |
قاعدة البيانات: | OpenAIRE |
تدمد: | 10970126 09598103 |
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