التفاصيل البيبلوغرافية
| العنوان: |
Combined maximum-quantum and DOSY 3D experiments provide enhanced resolution for small molecules in mixtures |
| المؤلفون: |
Stefano Caldarelli, G. N. Manjunatha Reddy, Mehdi Yemloul |
| المصدر: |
Magnetic Resonance in Chemistry. 55:492-497 |
| بيانات النشر: |
Wiley, 2016. |
| سنة النشر: |
2016 |
| مصطلحات موضوعية: |
010405 organic chemistry, Chemistry, Resolution (electron density), Analytical chemistry, General Chemistry, 010402 general chemistry, 01 natural sciences, Molecular physics, Spectral line, 0104 chemical sciences, NMR spectra database, Molecule, General Materials Science, Projection plane, Sensitivity (control systems), Diffusion (business), Spectroscopy |
| الوصف: |
We illustrate here as the combination of high-order maximum-quantum (MaxQ) and Diffusion-Ordered SpectroscopY (DOSY) NMR experiments in a 3D layout allows superior resolution for crowded NMR spectra. Non-uniform sampling (NUS) allows compressing the experimental time effectively to reasonable durations. Because diffusion effects were encoded within multiple-quantum coherences, increased sensitivity to magnetic field gradients is observed, requiring compensation for convection effects. The experiment was demonstrated on the spectra of a mix of small polyaromatic molecules. Specifically, in the case analyzed, the experiment provided an extreme simplification through the MaxQDOSY-MaxQ projection plane that presents one peak per molecule. Copyright © 2016 John Wiley & Sons, Ltd. |
| تدمد: |
0749-1581 |
| URL الوصول: |
https://explore.openaire.eu/search/publication?articleId=doi_________::558c2c89e592a13cfda61d74fdc011c8
https://doi.org/10.1002/mrc.4465 |
| حقوق: |
OPEN |
| رقم الأكسشن: |
edsair.doi...........558c2c89e592a13cfda61d74fdc011c8 |
| قاعدة البيانات: |
OpenAIRE |
