Tetrahedral μ4-chloride and in situ generated octahedral μ6-sulfide templating Co8 complexes with different distortions of the cube
| العنوان: | Tetrahedral μ4-chloride and in situ generated octahedral μ6-sulfide templating Co8 complexes with different distortions of the cube |
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| المؤلفون: | Xiu-Juan Tian, Yan-Ru Zhang, Xian-Ming Zhang, You-Zhu Yu, Yu-Hua Guo |
| المصدر: | Chemical Communications. 56:4236-4239 |
| بيانات النشر: | Royal Society of Chemistry (RSC), 2020. |
| سنة النشر: | 2020 |
| مصطلحات موضوعية: | Diethanolamine, Materials science, Sulfide, 010402 general chemistry, 01 natural sciences, Catalysis, chemistry.chemical_compound, Materials Chemistry, medicine, Antiferromagnetism, chemistry.chemical_classification, 010405 organic chemistry, Metals and Alloys, General Chemistry, 0104 chemical sciences, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, Rhombohedron, Crystallography, Octahedron, chemistry, Triethanolamine, Ceramics and Composites, Tetrahedron, Cube, medicine.drug |
| الوصف: | Herein two unprecedented octanuclear Co8 clusters are presented, [Cl@Co8 (TEOA)4(CH3CN)Cl3] (1) and [S@Co8(DEOA)6(NCS)2] (2) (H3TEOA = triethanolamine, H2DEOA = diethanolamine), in which tetrahedral μ4-chloride and in situ generated octahedral μ6-sulfide are used as templates. In spite of them being derivatives of cubes, eight Co atoms in 1 consist of two co-centered tetrahedra of different sizes, whereas in 2 they appear as a rhombohedron formed via elongating a cube along the C3-axis direction. Strong intra-cluster antiferromagnetic interactions were found. |
| تدمد: | 1364-548X 1359-7345 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::56e62e00d7f8fb577d8c35cb45275f45 https://doi.org/10.1039/d0cc01320j |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi...........56e62e00d7f8fb577d8c35cb45275f45 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 1364548X 13597345 |
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