Dielectric relaxation under pressure in granular dielectrics containing water: Compensation rule for the activation parameters

التفاصيل البيبلوغرافية
العنوان: Dielectric relaxation under pressure in granular dielectrics containing water: Compensation rule for the activation parameters
المؤلفون: Anthony N. Papathanassiou, J. Grammatikakis, I. Sakellis
المصدر: Solid State Ionics. :1-4
بيانات النشر: Elsevier BV, 2012.
سنة النشر: 2012
مصطلحات موضوعية: Materials science, Enthalpy, Thermodynamics, General Chemistry, Dielectric, Condensed Matter Physics, Granular material, law.invention, Volume (thermodynamics), law, Relaxation (physics), General Materials Science, Dielectric loss, Hydrostatic equilibrium, Porosity
الوصف: The dielectric relaxation of water-filled granular dielectrics under hydrostatic compression is investigated in the frequency domain. The activation volume and activation enthalpy governing a dominant relaxation mechanism of sandstone partially saturated with water are determined experimentally for the first time. The present results combined with recently published results for various wetted porous dielectrics indicate that, despite the complexity of this class of matter, such as heterogeneity of composition and micro-structural landscape and their disordered environment, a compensation rule between the absolute value of the activation volume and enthalpy is likely to be valid. The proportionality constant is determined by the isothermal bulk modulus and its pressure derivative, according to an earlier thermodynamic elastic model.
تدمد: 0167-2738
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::5a33912a4880f00daa78f5cf17067310
https://doi.org/10.1016/j.ssi.2011.12.011
حقوق: CLOSED
رقم الأكسشن: edsair.doi...........5a33912a4880f00daa78f5cf17067310
قاعدة البيانات: OpenAIRE